Carl McBride at 14:15, 10 December 2009

2009-12-10T14:15:06Z

← Older revision		Revision as of 16:15, 10 December 2009
Line 6:		Line 6:
	where <math>F</math> is the number of [[intensive properties\| intensive parameters]], <math>P</math> is the number of [[Phase diagrams \| phases]] and <math>C</math> is the number of components.		where <math>F</math> is the number of [[intensive properties\| intensive parameters]], <math>P</math> is the number of [[Phase diagrams \| phases]] and <math>C</math> is the number of components.
	==Derivation==		==Derivation==
			<ref>David Ruelle "Statistical mechanics: rigorous results" World Scientific Publishing (1969) § 7.5 (pp. 190-192) ISBN 978-981-02-3862-9</ref>
			<ref>[http://dx.doi.org/10.1007/BF02070248 G. Gutiérrez "Gibbs' phase rule revisited", Theoretical and Mathematical Physics '''108''' pp. 1222-1224 (1996)]</ref>

	==References==		==References==
	<references/>		<references/>
	~~'''Related reading'''~~
	*David Ruelle "Statistical mechanics: rigorous results" World Scientific Publishing (1969) § 7.5 (pp. 190-192) ISBN 978-981-02-3862-9
	*[http://dx.doi.org/10.1007/BF02070248 G. Gutiérrez "Gibbs' phase rule revisited", Theoretical and Mathematical Physics '''108''' pp. 1222-1224 (1996)]


	[[category: classical thermodynamics]]		[[category: classical thermodynamics]]

Carl McBride: New page: '''Gibbs phase rule''' Josiah Willard Gibbs "On the Equilibrium of Heterogeneous Substances", Transactions of the Connecticut Academy '''III''' pp. 108-248 (1876) [http://gallica.bnf...

2009-12-10T13:57:07Z

New page: '''Gibbs phase rule''' <ref>Josiah Willard Gibbs "On the Equilibrium of Heterogeneous Substances", Transactions of the Connecticut Academy '''III''' pp. 108-248 (1876) [http://gallica.bnf...

New page

'''Gibbs phase rule''' <ref>Josiah Willard Gibbs "On the Equilibrium of Heterogeneous Substances", Transactions of the Connecticut Academy '''III''' pp. 108-248 (1876) [http://gallica.bnf.fr/ark:/12148/bpt6k95192s (page images on gallica)]</ref>
<ref>Josiah Willard Gibbs "On the Equilibrium of Heterogeneous Substances", Transactions of the Connecticut Academy '''III''' pp. 343-524 (1878) [http://gallica.bnf.fr/ark:/12148/bpt6k95192s (page images on gallica)]</ref> states that

:<math>F=C-P+2</math>

where <math>F</math> is the number of [[intensive properties| intensive parameters]], <math>P</math> is the number of [[Phase diagrams | phases]] and <math>C</math> is the number of components.
==Derivation==
==References==
<references/>
'''Related reading'''
*David Ruelle "Statistical mechanics: rigorous results" World Scientific Publishing (1969) § 7.5 (pp. 190-192) ISBN 978-981-02-3862-9
*[http://dx.doi.org/10.1007/BF02070248 G. Gutiérrez "Gibbs' phase rule revisited", Theoretical and Mathematical Physics '''108''' pp. 1222-1224 (1996)]

[[category: classical thermodynamics]]

Gibbs phase rule - Revision history

Carl McBride at 14:15, 10 December 2009

Carl McBride: New page: '''Gibbs phase rule''' Josiah Willard Gibbs "On the Equilibrium of Heterogeneous Substances", Transactions of the Connecticut Academy '''III''' pp. 108-248 (1876) [http://gallica.bnf...