Wohl equation of state: Difference between revisions
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The ''' | The '''Wohl''' [[equations of state| equation of state]] is given by<ref>A. Wohl "Investigation of the condition equation", Zeitschrift für Physikalische Chemie (Leipzig) '''87''' pp. 1-39 (1914) </ref> | ||
:<math>\left[ p + \frac{a}{Tv(v-b)} - \frac{c}{T^2v^3} \right] (v-b) = RT</math> | :<math>\left[ p + \frac{a}{Tv(v-b)} - \frac{c}{T^2v^3} \right] (v-b) = RT</math> | ||
where | where (Eq. 10 in <ref>[http://dx.doi.org/10.1021/ie50663a005 K. K. Shah and G. Thodos "A Comparison of Equations of State", Industrial & Engineering Chemistry '''57''' pp. 30-37 (1965)]</ref>): | ||
:<math>\left. a \right.= 6P_cT_cv_c^2</math> | :<math>\left. a \right.= 6P_cT_cv_c^2</math> | ||
Latest revision as of 14:39, 22 September 2010
The Wohl equation of state is given by[1]
=RT}](https://wikimedia.org/api/rest_v1/media/math/render/svg/a65e35111c27738c5fd6503da4df6da239c5986b)
where (Eq. 10 in [2]):
and
where is the pressure, is the temperature and is the molar gas constant. is the critical temperature and is the pressure at the critical point.
References[edit]
- ↑ A. Wohl "Investigation of the condition equation", Zeitschrift für Physikalische Chemie (Leipzig) 87 pp. 1-39 (1914)
- ↑ K. K. Shah and G. Thodos "A Comparison of Equations of State", Industrial & Engineering Chemistry 57 pp. 30-37 (1965)