Ideal gas Helmholtz energy function: Difference between revisions
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Carl McBride (talk | contribs) m (New page: From equations :<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math> and :<math>A=-k_B T \ln Q_{NVT}</math> one has :<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}...) |
Carl McBride (talk | contribs) m (defined a couple of terms) |
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From equations | From equations | ||
:<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math> | :<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math> | ||
and | for the [[ Ideal gas partition function | canonical ensemble partition function for an ideal gas]], and | ||
:<math>A=-k_B T \ln Q_{NVT}</math> | :<math>\left.A\right.=-k_B T \ln Q_{NVT}</math> | ||
one has | for the [[Helmholtz energy function]], one has | ||
:<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}{\Lambda^{3}}\right)</math> | :<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}{\Lambda^{3}}\right)</math> | ||
::<math>=-k_BT\left(-\ln N! + N\ln\frac{VN}{\Lambda^3N}\right)</math> | ::<math>=-k_BT\left(-\ln N! + N\ln\frac{VN}{\Lambda^3N}\right)</math> | ||
Line 11: | Line 11: | ||
one arrives at | one arrives at | ||
<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math> | :<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math> | ||
where <math>\Lambda</math>is the [[de Broglie thermal wavelength]] and <math>k_B</math> is the [[Boltzmann constant]]. | |||
[[Category:Ideal gas]] | |||
[[Category:Statistical mechanics]] |
Latest revision as of 11:19, 4 August 2008
From equations
for the canonical ensemble partition function for an ideal gas, and
for the Helmholtz energy function, one has
using Stirling's approximation
one arrives at
where is the de Broglie thermal wavelength and is the Boltzmann constant.