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(New page: The mechanical '''work''', ''W'', performed in ''compressing'' a gas is given by :<math>W = - \int_\alpha^\beta p ~dV</math> where <math>\alpha</math> and <math>\beta</math> are points i...)
 
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The mechanical '''work''', ''W'', performed in ''compressing'' a gas is given by
The mechanical '''work''', ''W'', performed ''upon'' a gas is given by


:<math>W = - \int_\alpha^\beta p ~dV</math>
:<math>W = - \int_\alpha^\beta p ~dV</math>


where <math>\alpha</math> and <math>\beta</math> are points in state space, ''p'' is the [[pressure]]
where <math>\alpha</math> and <math>\beta</math> are points in state space, ''p'' is the [[pressure]]
and ''V'' is the volume.
and ''V'' is the volume. The mechanical work done ''by'' the gas has the opposite sign (a common
source of mistakes).
 
For reversible changes, where the system evolves through a succession of equilibrium states, one has
 
:<math>\left.dW\right.=-p~dV  </math>
 
and for irreversible changes
 
:<math>\left.dW\right. > -p~dV </math>
 
[[category: classical thermodynamics]]
[[category: classical thermodynamics]]

Latest revision as of 10:22, 5 July 2011

The mechanical work, W, performed upon a gas is given by

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle W = - \int_\alpha^\beta p ~dV}

where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \alpha} and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \beta} are points in state space, p is the pressure and V is the volume. The mechanical work done by the gas has the opposite sign (a common source of mistakes).

For reversible changes, where the system evolves through a succession of equilibrium states, one has

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left.dW\right.=-p~dV }

and for irreversible changes

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left.dW\right. > -p~dV }