Ideal gas Helmholtz energy function: Difference between revisions

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From equations  
From equations  
:<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math>
:<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math>
and  
for the [[ Ideal gas partition function | canonical ensemble partition function for an ideal gas]], and  
:<math>\left.A\right.=-k_B T \ln Q_{NVT}</math>
:<math>\left.A\right.=-k_B T \ln Q_{NVT}</math>
one has
for the [[Helmholtz energy function]], one has
:<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}{\Lambda^{3}}\right)</math>
:<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}{\Lambda^{3}}\right)</math>
::<math>=-k_BT\left(-\ln N! + N\ln\frac{VN}{\Lambda^3N}\right)</math>
::<math>=-k_BT\left(-\ln N! + N\ln\frac{VN}{\Lambda^3N}\right)</math>
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:<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math>
:<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math>


where <math>\Lambda</math>is the [[de Broglie thermal wavelength]] and <math>k_B</math> is the [[Boltzmann constant]].
[[Category:Ideal gas]]
[[Category:Ideal gas]]
[[Category:Statistical mechanics]]
[[Category:Statistical mechanics]]

Latest revision as of 12:19, 4 August 2008

From equations

QNVT=1N!(VΛ3)N

for the canonical ensemble partition function for an ideal gas, and

A=−kBTlnQNVT

for the Helmholtz energy function, one has

A=−kBT(ln1N!+NlnVΛ3)
=−kBT(−lnN!+NlnVNΛ3N)
=−kBT(−lnN!+NlnNΛ3ρ)

using Stirling's approximation

=−kBT(−NlnN+N+NlnN−NlnΛ3ρ)

one arrives at

A=NkBT(lnΛ3ρ−1)

where Λis the de Broglie thermal wavelength and kB is the Boltzmann constant.