Ideal gas Helmholtz energy function: Difference between revisions
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Carl McBride (talk | contribs) m (defined a couple of terms) |
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From equations | From equations | ||
:<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math> | :<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math> | ||
and | for the [[ Ideal gas partition function | canonical ensemble partition function for an ideal gas]], and | ||
:<math>\left.A\right.=-k_B T \ln Q_{NVT}</math> | :<math>\left.A\right.=-k_B T \ln Q_{NVT}</math> | ||
one has | for the [[Helmholtz energy function]], one has | ||
:<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}{\Lambda^{3}}\right)</math> | :<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}{\Lambda^{3}}\right)</math> | ||
::<math>=-k_BT\left(-\ln N! + N\ln\frac{VN}{\Lambda^3N}\right)</math> | ::<math>=-k_BT\left(-\ln N! + N\ln\frac{VN}{\Lambda^3N}\right)</math> | ||
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:<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math> | :<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math> | ||
where <math>\Lambda</math>is the [[de Broglie thermal wavelength]] and <math>k_B</math> is the [[Boltzmann constant]]. | |||
[[Category:Ideal gas]] | [[Category:Ideal gas]] | ||
[[Category:Statistical mechanics]] | [[Category:Statistical mechanics]] |
Latest revision as of 11:19, 4 August 2008
From equations
for the canonical ensemble partition function for an ideal gas, and
for the Helmholtz energy function, one has
using Stirling's approximation
one arrives at
where is the de Broglie thermal wavelength and is the Boltzmann constant.