Enthalpy: Difference between revisions

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(Added a couple of references)
m (Slight tidy)
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:<math>\left.H\right.=U+pV</math>
:<math>\left.H\right.=U+pV</math>


where <math>U</math>  is the [[internal energy]], <math>p</math> is the [[pressure]], <math>V</math> is the volume and ''(-pV)'' is a ''conjugate pair''. The differential of this function is
where <math>U</math>  is the [[internal energy]], <math>p</math> is the [[pressure]], <math>V</math> is the volume.
<math>pV</math> is a ''conjugate pair''. The differential of this function is


:<math>\left.dH\right.=dU+pdV+Vdp</math>
:<math>\left.dH\right.=dU+pdV+Vdp</math>
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:<math>\left.dH\right.=TdS +Vdp</math>
:<math>\left.dH\right.=TdS +Vdp</math>


For ''H(S,p)'' we have the following ''total differential''
For <math>H(S,p)</math> we have the following ''total differential''


:<math>dH=\left(\frac{\partial H}{\partial S}\right)_p dS + \left(\frac{\partial H}{\partial p}\right)_S dp</math>
:<math>dH=\left(\frac{\partial H}{\partial S}\right)_p dS + \left(\frac{\partial H}{\partial p}\right)_S dp</math>

Revision as of 17:06, 12 March 2012

Enthalpy () [1][2] is defined as:

where is the internal energy, is the pressure, is the volume. Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle pV} is a conjugate pair. The differential of this function is

From the Second law of thermodynamics one obtains

thus we arrive at

For Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle H(S,p)} we have the following total differential

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle dH=\left(\frac{\partial H}{\partial S}\right)_p dS + \left(\frac{\partial H}{\partial p}\right)_S dp}

References