Enthalpy: Difference between revisions
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Carl McBride (talk | contribs) (Added a couple of references) |
Carl McBride (talk | contribs) m (Slight tidy) |
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:<math>\left.H\right.=U+pV</math> | :<math>\left.H\right.=U+pV</math> | ||
where <math>U</math> is the [[internal energy]], <math>p</math> is the [[pressure]], <math>V</math> is the volume | where <math>U</math> is the [[internal energy]], <math>p</math> is the [[pressure]], <math>V</math> is the volume. | ||
<math>pV</math> is a ''conjugate pair''. The differential of this function is | |||
:<math>\left.dH\right.=dU+pdV+Vdp</math> | :<math>\left.dH\right.=dU+pdV+Vdp</math> | ||
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:<math>\left.dH\right.=TdS +Vdp</math> | :<math>\left.dH\right.=TdS +Vdp</math> | ||
For | For <math>H(S,p)</math> we have the following ''total differential'' | ||
:<math>dH=\left(\frac{\partial H}{\partial S}\right)_p dS + \left(\frac{\partial H}{\partial p}\right)_S dp</math> | :<math>dH=\left(\frac{\partial H}{\partial S}\right)_p dS + \left(\frac{\partial H}{\partial p}\right)_S dp</math> | ||
Revision as of 17:06, 12 March 2012
Enthalpy () [1][2] is defined as:
where is the internal energy, is the pressure, is the volume. Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle pV} is a conjugate pair. The differential of this function is
From the Second law of thermodynamics one obtains
thus we arrive at
For Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle H(S,p)} we have the following total differential
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle dH=\left(\frac{\partial H}{\partial S}\right)_p dS + \left(\frac{\partial H}{\partial p}\right)_S dp}
References
- ↑ J. P. Dalton "Researches on the Joule-Kelvin effect, especially at low temperatures. I. Calculations for hydrogen", KNAW Proceedings 11 pp. 863-873 (1909)
- ↑ Irmgard K. Howard "H Is for Enthalpy, Thanks to Heike Kamerlingh Onnes and Alfred W. Porter", Journal of Chemical Education 79 pp. 697-698 (2002)