Ideal gas Helmholtz energy function: Difference between revisions

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one arrives at  
one arrives at  


<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math>
:<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math>
 
[[Category:Ideal gas]]
[[Category:Statistical mechanics]]

Revision as of 13:05, 27 February 2007

From equations

QNVT=1N!(VΛ3)N

and

A=−kBTlnQNVT

one has

A=−kBT(ln1N!+NlnVΛ3)
=−kBT(−lnN!+NlnVNΛ3N)
=−kBT(−lnN!+NlnNΛ3ρ)

using Stirling's approximation

=−kBT(−NlnN+N+NlnN−NlnΛ3ρ)

one arrives at

A=NkBT(lnΛ3ρ−1)