Widom-Rowlinson model: Difference between revisions
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:<math> V \left( r_{ij} \right) = V_{HS}(r_{ij}); </math> if <math> i </math> and <math> j</math> belong to different species, | :<math> V \left( r_{ij} \right) = V_{HS}(r_{ij}); </math> if <math> i </math> and <math> j</math> belong to different species, | ||
with <math> V_{HS}(R) </math> is the [[hard sphere]] pair potential | with <math> V_{HS}(R) </math> is the [[hard sphere model | hard sphere]] pair potential | ||
== References == | == References == | ||
#[http://dx.doi.org/10.1063/1.1673203 B. Widom and J. S. Rowlinson, "New Model for the Study of Liquid–Vapor Phase Transitions", J. Chem. Phys. '''52''', pp. 1670-1684 (1970)] | #[http://dx.doi.org/10.1063/1.1673203 B. Widom and J. S. Rowlinson, "New Model for the Study of Liquid–Vapor Phase Transitions", J. Chem. Phys. '''52''', pp. 1670-1684 (1970)] | ||
[[Category: Models]] | [[Category: Models]] |
Revision as of 14:24, 21 March 2007
The Widom-Rowlinson model (Ref. 1) for mixtures takes the form:
- ; if and are particles of the same species
- if and belong to different species,
with is the hard sphere pair potential