Gibbs-Duhem integration

CURRENTLY THIS ARTICLE IS UNDER CONSTRUCTION

History

The so-called Gibbs-Duhem Integration referes to a number of methods that couple molecular simulation techniques with thermodynamic equations in order to draw phase coexistence lines.

The method was proposed by Kofke (Ref 1-2).

Basic Features

Consider two thermodynamic phases: $\alpha ,\beta$, at thermodynamic equilibrium at certain conditions. The thermodynamic equilibrium implies:

• Equal temperature in both phases: $T=T_{\alpha }=T_{\beta }$, i.e. thermal equilbirum.
• Equal pressure in both phases $p=p_{\alpha }=p_{\beta }$, i.e. mechanical equilbrium.
• Equal chemical potentials for the components $\mu _{i}=\mu _{i\alpha }=\mu _{i\beta }$, i.e. material equilibrium.

In addition if we are dealing with a statistical mechanics model, with certain parameters that we can represent as $\lambda$ , the model should be the same in both phases.

Example: phase equilibria of one-compoment system

Notice: The derivation that follows is just a particular route to perform the integration

• Consider that at given conditions of $T,p,\lambda$ two phases of the systems are at equilibrium, this implies:

$\mu _{\alpha }\left(T,p,\lambda \right)=\mu _{\beta }\left(T,p,\lambda \right)$

Given the thermal equilibrium we can also write:

$\beta \mu _{\alpha }\left(\beta ,\beta p,\lambda \right)=\beta \mu _{\beta }\left(\beta ,\beta p,\lambda \right)$

When a differential change of the conditions is performed we wil have for any phase:

$d\mu =\left({\frac {\partial \mu }{\partial T}}\right)_{p,\lambda }dT+\left({\frac {\partial \mu }{\partial p}}\right)_{T,\lambda }dp+\left({\frac {\partial \mu }{\partial \lambda }}\right)_{T,p}d\lambda .$

Taking into account that $\mu$ is the Gibbs free energy per particle:

TO BE CONTINUED .. soon

References

1. David A. Kofke, Gibbs-Duhem integration: a new method for direct evaluation of phase coexistence by molecular simulation, Mol. Phys. 78 , pp 1331 - 1336 (1993)
2. David A. Kofke, Direct evaluation of phase coexistence by molecular simulation via integration along the saturation line, J. Chem. Phys. 98 ,pp. 4149-4162 (1993)