Wohl equation of state: Difference between revisions

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:<math>\left[ p + \frac{a}{Tv(v-b)} - \frac{c}{T^2v^3} \right] (v-b) = RT</math>
:<math>\left[ p + \frac{a}{Tv(v-b)} - \frac{c}{T^2v^3} \right] (v-b) = RT</math>


where
where <ref>Note: these equations need to be checked</ref>


:<math>\left. a \right.= 6P_cT_cv_c^2</math>
:<math>\left. a \right.= 6P_cT_cv_c^2</math>

Revision as of 11:41, 22 September 2010

The Wohl equation of state is given by[1]

where [2]

and

where is the pressure, is the temperature and is the molar gas constant. is the critical temperature and is the pressure at the critical point.

References

  1. A. Wohl "Investigation of the condition equation", Zeitschrift für Physikalische Chemie (Leipzig) 87 pp. 1-39 (1914)
  2. Note: these equations need to be checked