Thermodynamic relations

These thermodynamic relations are also known as coefficient relations.

$T=\left({\frac {\partial U}{\partial S}}\right)_{V}$

$p=-\left({\frac {\partial U}{\partial V}}\right)_{S}$

$T=\left({\frac {\partial H}{\partial S}}\right)_{p}$

$V=\left({\frac {\partial H}{\partial p}}\right)_{S}$

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle S=-\left({\frac {\partial A}{\partial T}}\right)_{V}}

$p=-\left({\frac {\partial A}{\partial V}}\right)_{T}$

$S=-\left({\frac {\partial G}{\partial T}}\right)_{p}$

$V=\left({\frac {\partial G}{\partial p}}\right)_{T}$

where

• $H$ is the enthalpy
• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T} is the temperature
• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle G} is the Gibbs energy function
• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle U} is the internal energy,
• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle V} is the volume
• $A$ is the Helmholtz energy function
• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p} is the pressure
• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle S} is the entropy

See also

• Maxwell's relations
• Bridgman thermodynamic formulas