Widom-Rowlinson model: Difference between revisions

From SklogWiki
Jump to navigation Jump to search
mNo edit summary
No edit summary
Line 5: Line 5:
:<math> V \left( r_{ij} \right) =  V_{HS}(r_{ij});  </math> if <math> i </math> and <math> j</math> belong to different species,
:<math> V \left( r_{ij} \right) =  V_{HS}(r_{ij});  </math> if <math> i </math> and <math> j</math> belong to different species,


with <math> V_{HS}(R) </math> is the [[hard sphere]] pair potential
with <math> V_{HS}(R) </math> is the [[hard sphere model | hard sphere]] pair potential


== References ==
== References ==
#[http://dx.doi.org/10.1063/1.1673203 B. Widom and J. S. Rowlinson, "New Model for the Study of Liquid–Vapor Phase Transitions", J. Chem. Phys. '''52''', pp. 1670-1684  (1970)]
#[http://dx.doi.org/10.1063/1.1673203 B. Widom and J. S. Rowlinson, "New Model for the Study of Liquid–Vapor Phase Transitions", J. Chem. Phys. '''52''', pp. 1670-1684  (1970)]
[[Category: Models]]
[[Category: Models]]

Revision as of 13:24, 21 March 2007

The Widom-Rowlinson model (Ref. 1) for mixtures takes the form:

V(rij)=0; if i and j are particles of the same species
V(rij)=VHS(rij); if i and j belong to different species,

with VHS(R) is the hard sphere pair potential

References

  1. B. Widom and J. S. Rowlinson, "New Model for the Study of Liquid–Vapor Phase Transitions", J. Chem. Phys. 52, pp. 1670-1684 (1970)