Ideal gas Helmholtz energy function: Difference between revisions

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:<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math>
:<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math>


where <math>\Lambda</math>is the [[de Broglie thermal wavelength]] and <math>k_B</math> is the [[Boltzmann constant]].
[[Category:Ideal gas]]
[[Category:Ideal gas]]
[[Category:Statistical mechanics]]
[[Category:Statistical mechanics]]

Latest revision as of 12:19, 4 August 2008

From equations

QNVT=1N!(VΛ3)N

for the canonical ensemble partition function for an ideal gas, and

A=−kBTlnQNVT

for the Helmholtz energy function, one has

A=−kBT(ln1N!+NlnVΛ3)
=−kBT(−lnN!+NlnVNΛ3N)
=−kBT(−lnN!+NlnNΛ3ρ)

using Stirling's approximation

=−kBT(−NlnN+N+NlnN−NlnΛ3ρ)

one arrives at

A=NkBT(lnΛ3ρ−1)

where Λis the de Broglie thermal wavelength and kB is the Boltzmann constant.