Carnahan-Starling equation of state: Difference between revisions

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The equation of Carnahan-Starling is an approxiamate equation of state for the fluid phase of the [[Hard Sphere]] model in three dimensions.
The equation of Carnahan-Starling is an approximate equation of state for the fluid phase of the [[Hard Sphere]] model in three dimensions.
 
: <math>
Z = \frac{ p V}{N k_B T} = \frac{ 1 + \eta + \eta^2 - \eta^3 }{(1-\eta)^3 }.
</math>
 
where:
 
* <math> p </math> is the pressure
 
*<math> V </math> is the volume
 
*<math> N </math> is the number of particles
 
*<math> k_B  </math> is the [[Boltzmann]] constant
 
*<math> T </math> is the absolute temperature
 
*<math> \eta </math>, is the packing fraction:
 
:<math> \eta = \frac{ \pi }{6} \frac{ N \sigma^3 }{V} </math>
 
A reference is required here (please check)

Revision as of 18:59, 16 February 2007

The equation of Carnahan-Starling is an approximate equation of state for the fluid phase of the Hard Sphere model in three dimensions.

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle Z = \frac{ p V}{N k_B T} = \frac{ 1 + \eta + \eta^2 - \eta^3 }{(1-\eta)^3 }. }

where:

  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p } is the pressure
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle V } is the volume
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle N } is the number of particles
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle k_B } is the Boltzmann constant
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T } is the absolute temperature
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \eta } , is the packing fraction:
Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \eta = \frac{ \pi }{6} \frac{ N \sigma^3 }{V} }

A reference is required here (please check)