Carnahan-Starling equation of state: Difference between revisions

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== References ==
== References ==
     N. F. Carnahan and . E. Starling, J. Chem. Phys. '''51''' , 635-636 (1969)
     N.F.Carnahan and E.Starling, J. Chem. Phys. '''51''' , 635-636 (1969)

Revision as of 19:20, 16 February 2007

The equation of Carnahan-Starling is an approximate equation of state for the fluid phase of the Hard Sphere model in three dimensions.

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle Z={\frac {pV}{Nk_{B}T}}={\frac {1+\eta +\eta ^{2}-\eta ^{3}}{(1-\eta )^{3}}}.}

where:

  • is the pressure
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle V } is the volume
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle N } is the number of particles
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle k_B } is the Boltzmann constant
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T } is the absolute temperature
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \eta } is the packing fraction:
Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle \eta ={\frac {\pi }{6}}{\frac {N\sigma ^{3}}{V}}}
  • Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \sigma } is the Hard Sphere diameter

A reference is required here (please check)

References

   N.F.Carnahan and E.Starling, J. Chem. Phys. 51 , 635-636 (1969)