Ergodic hypothesis

The Ergodic hypothesis essentially states that an ensemble average (i.e. an instance of a Monte Carlo simulation) of an observable, $⟨O{⟩}_{\mu }$ is equivalent to the time average, ${\overline{O}}_T$ of an observable (i.e. molecular dynamics). i.e.

$\underset{T\to \mathrm{\infty }}{lim}{\overline{O}}_T(\{q_0(t)\},\{p_0(t)\})=⟨O{⟩}_{\mu }.$

A restatement of the ergodic hypothesis is to say that all allowed states are equally probable.

See also

• Markov chain

References

1. George D. Birkhoff, "Proof of the Ergodic Theorem", PNAS 17 pp. 656-660 (1931)
2. J. V. Neumann "Proof of the Quasi-ergodic Hypothesis", PNAS 18 pp. 70-82 (1932)
3. J. V. Neumann "Physical Applications of the Ergodic Hypothesis", PNAS 18 pp. 263-266 (1932)
4. G. D. Birkhoff and B. O. Koopman "Recent Contributions to the Ergodic Theory", PNAS 18 pp. 279-282 (1932)
5. Adrian Patrascioiu "The Ergodic-Hypothesis, A Complicated Problem in Mathematics and Physics", Los Alamos Science, 15 pp. 263- (1987)