Detailed balance

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Detailed balance (or the principle of microscopic reversibility) expresses the notion that at equilibrium, there are as many processes destroying situation $A$ and creating situation $B$ as there are processes destroying situation $B$ and creating situation $A$ (Ref 1 Appendix VII).

References

Related reading

Vasilios I. Manousiouthakis and Michael W. Deem "Strict detailed balance is unnecessary in Monte Carlo simulation", Journal of Chemical Physics 110 pp. 2753- (1999)

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