Dieterici equation of state
The Dieterici equation of state [1] is given by
where (Eq. 8 in [2]):
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle a = \frac{4R^2T_c^2}{P_ce^2}}
and
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle b=\frac{RT_c}{P_ce^2}}
where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p} is the pressure, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T} is the temperature and is the molar gas constant. Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T_c} is the critical temperature and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle P_c} is the pressure at the critical point.
Sadus modification
Sadus [3] proposed replacing the repulsive section of the Dieterici equation with the Carnahan-Starling equation of state, resulting in (Eq. 5):
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p = \frac{RT}{v} \frac{ 1 + \eta + \eta^2 - \eta^3 }{(1-\eta)^3 } e^{-a/RTv}}
where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \eta = b/4v } is the packing fraction.
References
- ↑ C. Dieterici, Ann. Phys. Chem. Wiedemanns Ann. 69, 685 (1899)
- ↑ K. K. Shah and G. Thodos "A Comparison of Equations of State", Industrial & Engineering Chemistry 57 pp. 30-37 (1965)
- ↑ Richard J. Sadus "Equations of state for fluids: The Dieterici approach revisited", Journal of Chemical Physics 115 pp. 1460-1462 (2001)