Consider a system with
spins in a row. The energy of the system will be given by
,
where each variable
can be either -1 or +1.
The partition function of the system will be:
,
where
represents the possible configuration of the N spins of the system,
and

Performing the sum of the possible values of
we get:
![{\displaystyle Q_{N}=\sum _{S_{1}}\sum _{S_{2}}e^{KS_{1}S_{2}}\sum _{S_{3}}e^{KS_{2}S_{3}}\cdots \sum _{S_{N-2}}e^{KS_{N-2}S_{N-1}}\left[2\cosh(KS_{N-1})\right]}](https://wikimedia.org/api/rest_v1/media/math/render/svg/2f50fd2dac113cb7796e8fc668815535891a6798)
Taking into account that
![{\displaystyle Q_{N}=\sum _{S_{1}}\sum _{S_{2}}e^{KS_{1}S_{2}}\sum _{S_{3}}e^{KS_{2}S_{3}}\cdots \sum _{S_{N-1}}e^{KS_{N-2}S_{N-1}}\left[2\cosh(K)\right]}](https://wikimedia.org/api/rest_v1/media/math/render/svg/cb95f34f38cb6fb130eb06e3ab9a81daad4a2074)
Therefore:
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle Q_{N} = \left( 2 \cosh K \right) Q_{N-1} }
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle Q_N = 2^{N} \left( \cosh K \right)^{N-1} \approx ( 2 \cosh K )^N }
The Helmholtz energy function in the thermodynamic limit will be
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle A = - N k_B T \log \left( 2 \cosh K \right) }
References