Ideal gas Helmholtz energy function

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Revision as of 14:04, 21 February 2007 by Carl McBride (talk | contribs) (New page: From equations :<math>Q_{NVT}=\frac{1}{N!} \left( \frac{V}{\Lambda^{3}}\right)^N</math> and :<math>A=-k_B T \ln Q_{NVT}</math> one has :<math>A=-k_BT\left(\ln \frac{1}{N!} + N\ln\frac{V}...)
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From equations

QNVT=1N!(VΛ3)N

and

A=−kBTlnQNVT

one has

A=−kBT(ln1N!+NlnVΛ3)
=−kBT(−lnN!+NlnVNΛ3N)
=−kBT(−lnN!+NlnNΛ3ρ)

using Stirling's approximation

=−kBT(−NlnN+N+NlnN−NlnΛ3ρ)

one arrives at

A=NkBT(lnΛ3ρ−1)