Compressibility: Difference between revisions

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The '''compressibility''', <math>Z</math>, is given by
The '''bulk modulus''' ''B'' gives the change in volume of a solid substance as the [[pressure]] on it is changed,
:<math>Z= \frac{pV}{Nk_BT}</math>


The '''bulk modulus''' <math>B</math> gives the change in volume of a solid substance as the pressure on it is changed,
:<math>B = -V \frac{\partial p}{\partial V}</math>


:<math>B = -V \frac{\partial P}{\partial V}</math>
The '''compressibility''' ''K'' or <math>\kappa</math>, is given by
 
The ''compressibility'' <math>K</math> or <math>\kappa</math>, is given by


:<math>\kappa =\frac{1}{B}</math>
:<math>\kappa =\frac{1}{B}</math>
 
==Isothermal compressibility==
The  '''isothermal compressibility''',  <math>\kappa_T</math> is given by
The  '''isothermal compressibility''',  <math>\kappa_T</math> is given by


:<math>\kappa_T =-\frac{1}{V} \left.\frac{\partial V}{\partial P}\right\vert_{T} =  \frac{1}{\rho} \left.\frac{\partial \rho}{\partial P}\right\vert_{T}</math>
:<math>\kappa_T =-\frac{1}{V} \left.\frac{\partial V}{\partial p}\right\vert_{T} =  \frac{1}{\rho} \left.\frac{\partial \rho}{\partial p}\right\vert_{T}</math>


(Note: in Hansen and McDonald the isothermal compressibility is written as <math>\chi_T</math>).
(Note: in Hansen and McDonald the isothermal compressibility is written as <math>\chi_T</math>).
where <math>\rho</math> is the ''particle number density'' given by
where <math>T</math> is the [[temperature]], <math>\rho</math> is the ''particle number density'' given by


:<math>\rho  = \frac{N}{V}</math>
:<math>\rho  = \frac{N}{V}</math>
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where <math>N</math> is the total number of particles in the system, i.e.
where <math>N</math> is the total number of particles in the system, i.e.


:<math>N = \int_V \rho(r,t)~{\rm d}r</math>
:<math>N = \int_V \rho({\mathbf r},t)~{\rm d}{\mathbf r}</math>
 
==Adiabatic compressibility==
The  '''adiabatic compressibility''',  <math>\kappa_S</math> is given by
 
:<math>\kappa_S =-\frac{1}{V} \left.\frac{\partial V}{\partial p}\right\vert_{S}</math>
 
where <math>S</math> is the [[entropy]].
==See also==
==See also==
The [[compressibility equation]] in [[statistical mechanics]].
The [[compressibility equation]] in [[statistical mechanics]].
==Compressibility of an Ideal Gas==
From the [[Equation of State: Ideal Gas | ideal gas law]]  we see that


:<math>Z= \frac{pV}{Nk_BT}=1</math>
[[category:classical thermodynamics]]
[[category:classical thermodynamics]]

Latest revision as of 18:07, 13 February 2008

The bulk modulus B gives the change in volume of a solid substance as the pressure on it is changed,

B=−V∂p∂V

The compressibility K or κ, is given by

κ=1B

Isothermal compressibility[edit]

The isothermal compressibility, κT is given by

κT=−1V∂V∂p|T=1ρ∂ρ∂p|T

(Note: in Hansen and McDonald the isothermal compressibility is written as χT). where T is the temperature, ρ is the particle number density given by

ρ=NV

where N is the total number of particles in the system, i.e.

N=∫Vρ(r,t)dr

Adiabatic compressibility[edit]

The adiabatic compressibility, κS is given by

κS=−1V∂V∂p|S

where S is the entropy.

See also[edit]

The compressibility equation in statistical mechanics.