The Wigner D-matrix (also known as the Wigner rotation matrix) is a square matrix, of dimension , given by
where and are Euler angles, and
where , known as Wigner's reduced d-matrix, is given by
This represents a rotation of about the (inital frame) axis.
Relation with spherical harmonic functions
The D-matrix elements with second index equal to zero, are proportional
to spherical harmonics (normalized to unity)
External links
References
- Eugene Paul Wigner "Gruppentheorie und ihre Anwendungen auf die Quantenmechanik der Atomspektren", Vieweg Verlag, Braunschweig (1931).
- Miguel A. Blanco, M. Flórez and M. Bermejo "Evaluation of the rotation matrices in the basis of real spherical harmonics", Journal of Molecular Structure: THEOCHEM 419 pp. 19-27 (1997)
- Holger Dachsel "Fast and accurate determination of the Wigner rotation matrices in the fast multipole method", Journal of Chemical Physics 124 144115 (2006)